Autor:	M. A. Liauw, Nils I. Jaeger, P. J. Plath, Cristian Hornoiu, Niculae I. Ionescu
Rok vydání:	2003
Předmět:	Thermokinetics Catalytic oxidation Chemistry Heat transfer Thermodynamics Activation energy Heat transfer coefficient Physics::Chemical Physics Physical and Theoretical Chemistry Condensed Matter Physics Catalysis Calorimeter Briggs–Rauscher reaction
Zdroj:	Journal of Thermal Analysis and Calorimetry. 73:851-858
ISSN:	1388-6150
DOI:	10.1023/a:1025894817063
Popis:	Thermokinetic oscillations obtained during the heterogeneous catalytic oxidation of methanol on Pd/LiAl5O8 in a dynamic calorimeter were characterized by an overall activation energy. This parameter was determined using the minimum and maximum values of the temperature oscillations. Using bifurcation diagrams with oxygen or methanol as bifurcation parameters. E values for all heating loss laws were calculated which are within the range for heterogeneous catalytic oxidation reactions. The obtained results have been discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0e637c7d1b0b9aaa32028fd637f5cdf9 https://doi.org/10.1023/a:1025894817063 Zobrazit plný text záznamu Full text from SpringerLink