Combinatorial characterisation of mixed conducting perovskites

Autor: Sarah Fearn, John A. Kilner, Lifeng Chen, Yong Zhang, Jeremy Rossiny, Julian R. G. Evans, Shoufeng Yang, Jennifer Julis
Rok vydání: 2008
Předmět:
Zdroj: Solid State Ionics. 179:1085-1089
ISSN: 0167-2738
DOI: 10.1016/j.ssi.2008.01.098
Popis: One of the most common types of structure which displays Mixed Electronic Ionic Conductivity is the ABO3 perovskite. The perovskite structure defines a very large range of possible oxide compositions and thus, for screening as potential SOFC cathodes, new methods must be used to obtain a complete picture of these MIEC materials. Combinatorial methods offer a route to identify the major trends in functional properties prior to full scale experiment. The system La1 ? xSrxCo1 ? y ? zMnyFezO3 + ? (LSCMF) has been synthesised by combinatorial methods using a robot ink-dip printer. A systematic set of experiments was performed to characterise the trends in crystal structure, and non-stoichiometry with composition. It is the first time that this LSCMF pseudo-ternary has been measured with a 10% B-site substitution of cobalt, manganese and iron
Databáze: OpenAIRE