Orientation of fluorescent probes and polymer segments in uniaxially drawn polycarbonate and Polyvinylchloride films as revealed by dichroism, fluorescence polarization and birefringence
| Autor: | Georg Hinrichsen, R. Neuert, F. D. Müller, H. Springer |
|---|---|
| Rok vydání: | 1983 |
| Předmět: |
chemistry.chemical_classification
Birefringence Materials science Polymers and Plastics Polymer Dichroism Polarization (waves) Fluorescence Crystallography Colloid and Surface Chemistry chemistry visual_art Materials Chemistry visual_art.visual_art_medium Organic chemistry Physical and Theoretical Chemistry Polycarbonate Glass transition Fluorescence anisotropy |
| Zdroj: | Colloid & Polymer Science. 261:800-804 |
| ISSN: | 1435-1536 0303-402X |
| DOI: | 10.1007/bf01421432 |
| Popis: | PVC- and PC-films doped with various fluorescent molecules were uniaxially drawn below and just above the glass transition temperature. The orientation of fluorescent probes and polymer segments is discussed, comparing Hermans' orientation factors evaluated from birefringence for the segments and from dichroism and fluorescence polarization for the probes. Moreover, the orientation of the fluorescent probes is related to that of hypothetical units, orientated according to the pseudoaffine deformation mechanism. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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