Autor:	T. A. Dik
Rok vydání:	2001
Předmět:	Ligand Spectral properties Inorganic chemistry Condensed Matter Physics chemistry.chemical_compound symbols.namesake Uranyl nitrate chemistry Nitrate Phase (matter) symbols Raman spectroscopy Spectroscopy Phosphine Vibrational spectra
Zdroj:	Journal of Applied Spectroscopy. 68:55-60
ISSN:	0021-9037
DOI:	10.1023/a:1019256902014
Popis:	The IR and Raman vibrational spectra of a number of uranyl nitrate complexes with tertiary aliphatic phosphine oxides in a solid phase and solutions have been investigated. It is found that the spectral characteristics of these complexes are independent of the state of aggregation of the substance. From the analysis of experimental and predicted data on vibrational spectra and application of the spectral signs of coordination of the NO3− ligand a conclusion is drawn on the formation of insular type structures. It is established that the presence of neutral organophosphorus ligands in the composition of the complexes does not exert any effect on the applicability of the spectral criteria of coordination of the nitrate acidoligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0e0cecb3829daeb2ed4a312feba2c0c4 https://doi.org/10.1023/a:1019256902014 Zobrazit plný text záznamu Full text from SpringerLink