Theoretical and experimental study of earth-abundant solar cell materials

Autor: Tingting Shi, Dewei Zhao, Feng Hong, Yanfa Yan, Wan-Jian Yin, Weijun Ke, Jie Ge, Alex Cimaroli, Y. Yue
Rok vydání: 2015
Předmět:
Zdroj: 2015 22nd International Workshop on Active-Matrix Flatpanel Displays and Devices (AM-FPD).
DOI: 10.1109/am-fpd.2015.7173196
Popis: In this paper, we present theoretical and experimental studies of two representative earth-abundant, thin-film solar cell materials: Cu 2 ZnSnS 4 and CH 3 NH 3 PbI 3 . Using first-principles density-functional theory, we show that both Cu 2 ZnSnS 4 and CH 3 NH 3 PbI 3 exhibit electronic and optical properties that are suitable for solar cell applications. However, the defect physics are rather different in these two earth-abundant solar cell materials: the dominant defects produce deep gap states in Cu 2 ZnSnS 4 but only shallow states in CH 3 NH 3 PbI 3 , indicating that CH 3 NH 3 PbI 3 is a more promising candidate for achieving high efficiency solar cells. Through the synthesis and characterization of Cu 2 ZnSnS 4 and CH 3 NH 3 PbI 3 -based thin-film solar cells, we show that CH 3 NH 3 PbI 3 -based thin-film solar cells exhibit significantly higher performance than Cu 2 ZnSnS 4 -based solar cells.
Databáze: OpenAIRE