Photoelectron–neutral–neutral coincidence studies of dissociative photodetachment

Autor: K. A. Hanold, Robert E. Continetti, C. R. Sherwood
Rok vydání: 1995
Předmět:
Zdroj: The Journal of Chemical Physics. 103:9876-9879
ISSN: 1089-7690
0021-9606
DOI: 10.1063/1.469954
Popis: Photoelectron–neutral–neutral coincidence spectra have been measured for the dissociative photodetachment of O4− (O4−+hν→O2+O2+e−) at 523 and 349 nm. The neutral photofragment translational energy spectrum, the photoelectron spectrum, and the correlations of the translational energy and photoelectron energy are presented here. The correlation spectra reveal phenomena that are not discernable in either one‐dimensional measurement. Features are observed which indicate that non‐Franck–Condon processes play a role in the dissociative photodetachment of O4− at 349 nm.
Databáze: OpenAIRE