ChemInform Abstract: Cyclopentadienone Cyclopentadienediyl Diselenoketals

Autor:	Georg Thaler, Fritz Sladky, Klaus Wurst
Rok vydání:	2010
Předmět:	Diffraction Crystallography chemistry.chemical_compound chemistry Cyclopentadienone Stereochemistry Potassium chemistry.chemical_element General Medicine Selenium
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199841174
Popis:	Reaction of di-tert-butylcyclopentadiene with excess potassium tert-butoxide in the presence of elemental selenium leads to cyclopentadienes bridged by two or three selenium atoms through one or two diselenoketal functionalities. 2,5,4′,6′-Tetra-tert-butyl-5′H-spirocyclopentane-1,2′-cyclopenta[b][1,3]diselena-2,4-diene (1) and 1,3,5,7-tetra-tert-butyl-3a,7a-dihydro-3a,7a-epi-selenodicyclopenta[b,e][1,4]diselenine (2) have been characterized by single-crystal X-ray diffraction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0ddaed9148f4731539de7d5e8ef6e181 https://doi.org/10.1002/chin.199841174 Zobrazit plný text záznamu Plný text