TMSCl-Promoted Electroreduction of Triphenylphosphine Oxide to Triphenylphosphine

Autor:	Hideo Tanaka, Tomotake Yano, Kazuma Kobayashi, Hiromu Kawakubo, Manabu Kuroboshi, Syogo Kamenoue
Rok vydání:	2011
Předmět:	Electrolysis Organic Chemistry Inorganic chemistry chemistry.chemical_element Electrochemistry Medicinal chemistry law.invention Anode chemistry.chemical_compound Transition metal chemistry law Triphenylphosphine Acetonitrile Platinum Triphenylphosphine oxide
Zdroj:	Synlett. 2011:582-584
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0030-1259529
Popis:	Direct reductive transformation of triphenylphosphine oxide to triphenylphosphine was performed successfully by electrolysis with TMSCl in an acetonitrile/Bu 4 NBr/(Zn anode)―(Pt cathode)/undivided cell/constant current electrolysis system. A plausible ECEC mechanism involving the formation of silylated phosphorus radical is proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0dc907ee6dbba858670220a1dc3fa008 https://doi.org/10.1055/s-0030-1259529 Zobrazit plný text záznamu