Syntheses of Biodegradable Functional Polymers by Radical Ring-Opening Polymerization of 2-Methylene-1,3,6-trioxocane
| Autor: | Yutaka Tokiwa, Yoichi Hiraguri |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
Environmental Engineering
Materials science Polymers and Plastics organic chemicals technology industry and agriculture Maleic anhydride macromolecular substances Ring-opening polymerization Biodegradable polymer Vinyl polymer chemistry.chemical_compound chemistry Methyl vinyl ketone Polymer chemistry Materials Chemistry Vinyl acetate Copolymer Radical initiator Organic chemistry |
| Zdroj: | Journal of Polymers and the Environment. 18:116-121 |
| ISSN: | 1572-8900 1566-2543 |
| Popis: | 2-Methylene-1,3,6-trioxocane (MTC) was polymerized via ring-opening in the presence of a radical initiator and the obtained polyester was biodegradable. MTC could also copolymerize with various vinyl monomers such as styrene, vinyl acetate, methyl vinyl ketone, N-vinyl-2-pyrrolidone, N-isopropyl acrylamide, and maleic anhydride. By copolymerizing MTC with these vinyl monomers in the presence of a radical initiator, we could obtain various biodegradable polymers with ester group introduced into the backbone. In addition the obtained copolymers exhibit certain functionalities such as photolysis, water-solubility, thermosensitivity, detergent builder, and water-absorbability. |
| Databáze: | OpenAIRE |
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