Ammonia rotations in ytterbiumhexaammine
| Autor: | Pierre Damay, C. Nöldeke, J. Dianoux, Françoise Leclercq, Werner Press, B. Asmussen, M. Foukani |
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| Rok vydání: | 1995 |
| Předmět: |
Neutron diffraction
General Physics and Astronomy Inelastic scattering Rotation Small-angle neutron scattering Inelastic neutron scattering Ammonia chemistry.chemical_compound chemistry Rectangular potential barrier Physics::Chemical Physics Physical and Theoretical Chemistry Atomic physics Astrophysics::Galaxy Astrophysics |
| Zdroj: | The Journal of Chemical Physics. 102:1122-1128 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.469170 |
| Popis: | The results of inelastic neutron scattering experiments on ytterbiumhexaammine are presented. At temperatures below 35 K, the dominant dynamical process is a uniaxial rotation of the ammonia in hindering potentials of about 35 meV. At higher temperatures, another type of ammonia motion is observed, which is described as reorientations of entire Yb(NH3)x complexes (x≊6). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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