ChemInform Abstract: Grubbs′ Catalyst Promoted Oxacycloisomerization: An Easy Route to Bicyclic Dihydrofurans and Tricyclic Acetals

Autor: Assya Taleb, Mokhtar Lahrech, Jérôme Thibonnet, Salih Hacini, Jean-Luc Parrain
Rok vydání: 2009
Předmět:
Zdroj: ChemInform. 40
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200944041
Popis: Oxacycloisomerization of 1-hydroxy-2-propargyl cyclic derivatives was catalyzed by the first-generation Grubbs catalyst (Grubbs I) and led to good yields of bicyclic dihydrofurans. Tricyclic acetals were also obtained from cyclic alkyne diols using the same experimental procedure.
Databáze: OpenAIRE