Organoboron compounds. 350. A mass-spectrometric study of the acylamidinates and acylaminopyridinates of boron

Autor:	L. I. Lavrinovich, V. A. Dorokhov, B. M. Mikhailov, O. S. Chizhov, B. M. Zolotarev
Rok vydání:	1979
Předmět:	Delocalized electron Organoboron compounds chemistry Fragmentation (mass spectrometry) Computational chemistry chemistry.chemical_element Organic chemistry General Chemistry Boron Mass spectrometric
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:70-74
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00925400
Popis:	1. The fragmentation of the dialkylborylacylamidinates and dialkylborylacylaminopyridinates is similar to the fragmentation of the dialkylborylimidoylamidinates which we studied earlier, differing from the latter in breakdown of the boron-containing ring. 2. Fragmentation with breakdown of the boron-containing ring proceeds more extensively in the dialkylboryl[2-(α-hydroxyalkyl)aminopyridinates] than in the dialkylboryl(2-acylaminopyridinate)s, compounds with delocalized π-electron systems.
Databáze:	OpenAIRE
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