Modification of silica nanoparticles with stereisomers of p-tert-butylthiacalix[4]arene containing four 2-oxo-2-{[3-(triethoxysilyl)prop-1-yl]amino}ethoxy substituents at the lower rim

Autor:	N. A. Losev, Ivan I. Stoikov, Alexander V. Gerasimov, L. S. Yakimova, R. V. Ziatdinova, V. G. Evtyugin, I. S. Teren’tev
Rok vydání:	2017
Předmět:	Aqueous solution 010405 organic chemistry General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Nitroaniline Silica nanoparticles Nitrophenol chemistry.chemical_compound Adsorption chemistry Alkoxy group Surface modification
Zdroj:	Russian Journal of General Chemistry. 87:1969-1976
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363217090122
Popis:	Three stereoisomers (cone, partial cone, and 1,3-alternate) of p-tert-butylthiacalix[4]arene bearing four anchor propyltriethoxysilane substituents at the lower rim were synthesized for the first time. Surface modification of silica nanoparticles (d = 12 nm) with the synthesized macrocycles gave novel hybride thiacalix [4]arene‒SiO2 particles. The obtained nanostructured adsorbents were found to efficiently extract nitroaromatic compounds from aqueous solutions. The partial cone and 1,3-alternate thiacalix[4]arene–SiO2 hybrid particles showed affinity to nitrophenols.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0d879ffd98a13e19cdfeff907a94c7c2 https://doi.org/10.1134/s1070363217090122 Zobrazit plný text záznamu Plný text ve formátu PDF