(1SR,8aRS)-1,2,3,5,6,7,8,8a-Octahydro-3-oxonaphthalene-1-carboxylic acid: catemeric hydrogen bonding in a bicyclic unsaturated γ-keto acid

Autor:	Mark Davison, Hugh W. Thompson, Roger A. Lalancette, Muhammad H. Malak
Rok vydání:	2007
Předmět:	chemistry.chemical_classification chemistry Bicyclic molecule Group (periodic table) Stereochemistry Hydrogen bond Carboxylic acid General Materials Science General Chemistry Keto acid Condensed Matter Physics Close contact
Zdroj:	Acta Crystallographica Section E Structure Reports Online. 63:o4014-o4014
ISSN:	1600-5368
DOI:	10.1107/s1600536807043425
Popis:	The title racemate (C11H14O3) aggregates in the solid as acid-to-ketone hydrogen-bonding catemers [O⋯O = 2.6557 (13) A and O—H⋯O = 170°], whose components are glide-related. The stereochemistry of the carboxyl group arises spontaneously during the synthesis. One inter­molecular C—H⋯O=C close contact was found.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0d572ad8fb8dcd60d4d2a2f43f7be097 https://doi.org/10.1107/s1600536807043425 Zobrazit plný text záznamu Plný text ve formátu PDF