Formation of Complexes in Benzene‐Oxalyl Chloride Solutions

Autor:	R. E. Kagarise, B. D. Saksena
Rok vydání:	1951
Předmět:	Acrolein General Physics and Astronomy Photochemistry Diacetyl Medicinal chemistry Acetyl bromide chemistry.chemical_compound symbols.namesake chemistry Oxalyl chloride Acetyl chloride symbols Physical and Theoretical Chemistry Crotonaldehyde Benzene Raman spectroscopy
Zdroj:	The Journal of Chemical Physics. 19:994-999
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.1748475
Popis:	Extinction coefficients have been obtained for solutions of oxalyl chloride diluted with benzene, n‐heptane, and me‐cyclohexane; and for solutions of diacetyl, acetyl bromide, acetyl chloride, α‐methyl acrolein, and crotonaldehyde diluted with benzene and n‐heptane. It has been possible to correlate the observed data in the infrared, Raman, and ultraviolet spectra of oxalyl chloride‐benzene solutions by postulating a complex formation of the type Ar+[COCl]2−.
Databáze:	OpenAIRE
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