AROMATIC HYDROXYLATION OF 2,4,6-TRIDEUTERIOTOLUENE BY O(3P) ATOMS WITH THE NIH SHIFT OF DEUTERIUM

Autor:	SakuraiHiroshi, MatsumotoHiroyuki, HoriAkira, TakamukuSetsuo
Rok vydání:	1978
Předmět:	Hydroxylation chemistry.chemical_compound NIH shift Deuterium chemistry Aromatic hydroxylation Microsome Liquid phase General Chemistry Ring (chemistry) Photochemistry Medicinal chemistry Gas phase
Zdroj:	Chemistry Letters. 7:467-470
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.1978.467
Popis:	Hydroxylation of 2,4,6-trideuteriotoluene by O(3P) atoms gave mixtures of tri- and di-deuteriocresol in liquid phase and in gas phase. The retention values of deuterium of aromatic ring in cresols produced by the hydroxylation were similar to those reported with microsomes. The mechanism of the NIH shift via a σ-complex intermediate is proposed.
Databáze:	OpenAIRE
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