The crystal structure of the 2D polymerized tetragonal phase of C60

Autor:	L. S. Kashevarova, V. A. Davydov, A. V. Dzyabchenko, B. Narymbetov, A. V. Rakhmanina, V. I. Kulakov, Viatcheslav N. Agafonov, René Céolin
Rok vydání:	2003
Předmět:	Diffraction Tetragonal crystal system Crystallography Polymerization Chemistry High pressure Phase (matter) General Physics and Astronomy Random combination Crystal structure Physical and Theoretical Chemistry Single crystal
Zdroj:	Chemical Physics Letters. 367:157-162
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(02)01526-9
Popis:	Single crystals of the 2D polymerized tetragonal phase of C60 without orientational domains were obtained under high pressure and high temperature. The crystal structure of this phase was resolved using single crystal X-ray diffraction data. The cell parameters are a=9.064(3) and c=15.039(8) A with the space group P42/mmc and Z=2. A structural model of this phase proposed early was confirmed and refined to final R=0.075. The structure is slightly disordered. It consists of a random combination of the P42/mmc layers (84%) and of the Immm layers (16%), along the c-axis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0d21de747a16de5e896b525a926c608a https://doi.org/10.1016/s0009-2614(02)01526-9 Zobrazit plný text záznamu Full Text from ScienceDirect