Mechanistic and synthetic aspects of intramolecular alkoxide–allene cyclizations

Autor:	Pamela Albaugh-Robertson, Philip Magnus
Rok vydání:	1984
Předmět:	Steric effects chemistry.chemical_classification Intramolecular reaction Stereochemistry Chemistry Allene Epoxide Reaction intermediate Medicinal chemistry chemistry.chemical_compound Intramolecular force Alkoxide Enol ether Molecular Medicine
Zdroj:	J. Chem. Soc., Chem. Commun.. :804-806
ISSN:	0022-4936
Popis:	Intramolecular cyclization of the methoxyallene–alkoxide adducts (1a) proceeds along two different pathways via a methoxyallyl radical to give either a dihydrofuran, or vinyl epoxide, depending upon the steric environment of the redical anion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0d18d7a8f0aa5073d841c8c42f918024 https://doi.org/10.1039/c39840000804 Zobrazit plný text záznamu