Efficient Ring Opening of Aziridines with Carboxylic Acids

Autor:	Swinderjeet Singh Kalra, Vinod K. Singh, Manoj Kumar, Shikha Gandhi
Rok vydání:	2008
Předmět:	Hydrolysis Amino esters Chemistry Organic Chemistry Diastereomer Organic chemistry Cleavage (embryo) Ring (chemistry) Catalysis
Zdroj:	Synthetic Communications. 38:1527-1532
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397910801928723
Popis:	An efficient ring cleavage of aziridines with acids has been studied in the absence of any catalyst. The hydrolysis of the products, amino esters, leads to the corresponding amino alcohols. The reaction has been extended to chiral cycloalkyl aziridines, leading to the formation of diastereomers. After separation, these diastereomers have been converted to optically pure amino alcohols in two steps.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0d0a0c758c744a1fc205848ff5a86794 https://doi.org/10.1080/00397910801928723 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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