Dielectric Study and Helical Pitch Measurements on a New Antiferroelectric Liquid Crystal

Autor: C. Destrade, A. Bouchta, J. P. Parneix, H. T. Nguyen, F. Bibonne, G. Joly, N. Isaert
Rok vydání: 1995
Předmět:
Zdroj: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 263:27-35
ISSN: 1058-725X
Popis: The dielectric dispersion in the ferroelecric and antiferroelectric phases of a new liquid crystal (S)-4-(1-methylheptyloxycarbonyl)-phenyl 4-(4-dodecyloxybenzoyloxy)benzoate has been investigated in the frequency range from 10 Hz to 10 MHz. The behaviour of the soft mode in SmA and the Goldstone mode in SmC* have been determined. Two dielectric relaxations have been recognized in the antiferroelectric SmC*A phase : the first one between 5 kHz and 50 kHz and the second one, also observable in the ferrielectric SmC*FI phase, around 1 MHz. In SmC*FI, a drastic change in the behaviour of the low frequency response has been found depending on whether the sample was heated or cooled. A sign reversal of the helical pitch has been determined inside the SmC*FI phase, leading to low pitch values of opposite sign in SmC*A and SmC*.
Databáze: OpenAIRE