High pressure synthesis of a bulky polymer of monocyanoacetylene

Autor: M. Yoshida, S. Fujiwara, H. Yamawaki, S. Usuba, A. Aoki, Y. Kakudate
Rok vydání: 1991
Předmět:
Zdroj: Synthetic Metals. 41:49-52
ISSN: 0379-6779
DOI: 10.1016/0379-6779(91)90994-g
Popis: A polymer of monocyanoacetylene was prepared by solid state reaction at high pressure. A black solid 5 mm in diameter and 2 mm in thickness was recovered after polymerization of the monomer crystal in a piston cylinder apparatus for 64 hours at 1.7 GPa and room temperature. The Raman and ir spectra of the reaction product indicated the formation of a conjugated linear polymer with the CN pendant group.
Databáze: OpenAIRE