Bis(4-nitrophenyl)tetrafluorosulfuranes: Synthesis, Isomerization and Structural Characterization

Autor:	Jens Osterodt, and Annette Kirsch, Peer Kirsch, Matthias Bremer
Rok vydání:	1999
Předmět:	Molecular model Octahedral symmetry Hypervalent molecule chemistry.chemical_element General Chemistry Biochemistry Sulfur Combinatorial chemistry Catalysis Colloid and Surface Chemistry chemistry Organic chemistry Carbon Isomerization Cis–trans isomerism
Zdroj:	Journal of the American Chemical Society. 121:11277-11280
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja9915495
Popis:	Due to their octahedral symmetry, otherwise not available for carbon based chemistry, hypervalent sulfur fluorides are very attractive as structural building blocks for functional organic materials. Direct fluorination offers a convenient access to multigram quantities of highly stable bis(4-nitrophenyl)tetrafluorosulfurane. Guided by molecular modeling, a novel catalytic process was devised to isomerize the predominantly formed cis isomer to the pure trans isomer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0d004fd47a3b7bd3a77b4a96123ea2dc https://doi.org/10.1021/ja9915495 Zobrazit plný text záznamu