Electrocatalytic Hydrogenation of Organic Compounds on a Poly[N-(5-hydroxypentyl)pyrrole] Film-Coated Electrode Incorporating Palladium Microparticles

Autor:	Nobuhiro Takano, Noboru Takeno, Akihito Nakade
Rok vydání:	1997
Předmět:	chemistry.chemical_classification Inorganic chemistry chemistry.chemical_element Halogenation General Chemistry Polymer Electrochemistry Catalysis chemistry.chemical_compound chemistry Electrode Benzyl group Pyrrole Palladium
Zdroj:	Bulletin of the Chemical Society of Japan. 70:837-840
ISSN:	1348-0634 0009-2673
Popis:	A poly[N-(5-hydroxypentyl)pyrrole] film-coated carbon-fiber electrode incorporating palladium metal microparticles was prepared and the catalytic ability in the electrochemical hydrogenation of organic compounds was investigated. This electrode exhibited a high catalytic ability and a strong physical stability with respect to hydrogen evolution. By using this electrode, the electrocatalytic hydrogenation for organic compounds in an organic solvent–buffer solution led to an efficient formation of hydrogenated products, such as saturated compounds, amino compounds, and hydroxy compounds, in high yields and current efficiencies. Furthermore, a catalytic polymer film electrode was successfully applied to the hydrogenative deprotection of a benzyl group and the dehalogenation of bromobenzene in electroreduction media.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0cf5b2e72c7d6adfbea6038a5f912aa6 https://doi.org/10.1246/bcsj.70.837 Zobrazit plný text záznamu