Gas-phase acidities of binary hydrides

Autor: Kermit C. Smyth, John R. Eyler, Melvin B. Comisarow, Larry K. Blair, John I. Brauman, Michael J. White
Rok vydání: 1971
Předmět:
Zdroj: Journal of the American Chemical Society. 93:6360-6362
ISSN: 1520-5126
0002-7863
DOI: 10.1021/ja00753a003
Popis: The preferred direction of proton transfer in a reaction between a hydride molecule and a hydride ion was studied in order to determine the relative acidities of some binary hydrides. Sufficient data are presented to make clear the periodic trends in acidities and the underlying trends in other fundamental thermochemical quantities which influence acidity. The bond dissociation energies and electron affinities of the hydrides considered are listed in a table.
Databáze: OpenAIRE