Photochemical studies of rancidity: The mechanism of rancidification

Autor:	Mayne R. Coe
Rok vydání:	1938
Předmět:	chemistry.chemical_classification Animal fat General Chemical Engineering Glyceride Organic Chemistry Nascent hydrogen Photochemistry Peroxide Aldehyde chemistry.chemical_compound Pigment chemistry visual_art Rancidification visual_art.visual_art_medium Organic chemistry Photosensitizer
Zdroj:	Oil & Soap. 15:230-236
ISSN:	1558-9331 0003-021X
Popis:	A theory is set forth for the mechanism of rancidification which is based on a disrupted photosynthesis in the case of vegetable oils and on the photosensitizing action of haemoglobin or other animal pigment that may be present in small amounts in animal fats such as lard. Nascent hydrogen is believed to be liberated from the photosensitizer (chlorophyll or animal pigment) which unites with molecular oxygen to form loosely combined or nascent hydrogen peroxide. This unstable peroxide unites with the unsaturated bond of the tri-glyceride to form a glyceride peroxide which in turn splits into an aldehyde and forms the rancid compound.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0cdd03bb5c1c4331434afc577158eff8 https://doi.org/10.1007/bf02639535 Zobrazit plný text záznamu Full text from SpringerLink