Mechanistic Insights into Oxidative Decomposition of exo-Tetrahydrodicyclopentadiene

Autor:	Jeong Sik Han, Joongyeon Kim, Byung Hun Jeong, Sun Hee Park, Cheong Hoon Kwon, Hogyu Han, Sung Hyun Kim
Rok vydání:	2013
Předmět:	General Energy Chemistry Mechanism (philosophy) Thermal decomposition Product formation Oxidative phosphorylation Physical and Theoretical Chemistry Photochemistry Decomposition Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	The Journal of Physical Chemistry C. 117:15933-15939
ISSN:	1932-7455 1932-7447
Popis:	We investigated the decomposition of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of O2 at various temperatures. It was found that conversion of exo-THDCP was faster in the presence of O2 as compared to in its absence. The O2-induced increase in the conversion of exo-THDCP was hardly affected by variations in temperature. In addition, the O2-induced increase in the rate of C10 product formation was higher than those of C10. We proposed the mechanism for the oxidative decomposition of exo-THDCP, which occurs independently of its thermal decomposition and induces distinct product formation near and below its thermal decomposition starting temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0cdb37ebb3740b1d94a0b46913852b15 https://doi.org/10.1021/jp404730g Zobrazit plný text záznamu