Electronic properties of pan-based carbon fibers—I

Autor: Ian L. Spain, K.J Volin, H.A Goldberg, Ilmar L. Kalnin
Rok vydání: 1983
Předmět:
Zdroj: Journal of Physics and Chemistry of Solids. 44:839-849
ISSN: 0022-3697
DOI: 10.1016/0022-3697(83)90018-5
Popis: Measurements of the resistivity of PAN-based fibers are reported for temperatures between 1.5 and 300 K. Particular care was taken to avoid sample heating problems during measurements. Fibers were heat-treated between ~ 1300°C to above 3000°C, corresponding to a wide range of elastic moduli (~ 35–112 Msi : 240–770 GPa). A particularly surprising result was the observation of a resistivity maximum for low modulus (35 Msi ~240 GPa) fiber below 50 K. Results are compared to those reported on bulk heat treated carbons and pyrocarbons. A qualitative discussion of the results is also given in terms of recent models of the electronic energy levels of carbon ribbons and turbostratic carbons.
Databáze: OpenAIRE