Relative solubility of tetrachlorohexafluorobisphenol-A polycarbonate in various compounds

Autor:	R. W. Mah, H. N. Beck, E. S. Sanders
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Polymers and Plastics Chemistry Organic solvent General Chemistry Polymer Surfaces Coatings and Films Hildebrand solubility parameter visual_art Materials Chemistry visual_art.visual_art_medium Organic chemistry Solubility Polycarbonate
Zdroj:	Journal of Applied Polymer Science. 47:2161-2167
ISSN:	1097-4628 0021-8995
DOI:	10.1002/app.1993.070471210
Popis:	The relative solubility of tetrachlorohexafluorobisphenol-A polycarbonate was observed in 127 organic compounds comprising 14 different chemical classes at room temperature and up to about 225°C. The polymer is soluble in numerous esters, ketones, halocarbons, heterocyclics, and amides. It is poorly soluble in alcohols and fluorocarbons. Correlation of observed solubility with Hildebrand total solubility parameters was poor; a much better correlation was observed with Hansen three-dimensional parameters. The solubility parameter of the polymer was estimated to be 9.1 (cal/cm3)1/2 (18.7 MPa1/2) from the averages of the Hansen parameters for 26 experimentally identified solvents. © 1993 John Wiley & Sons, Inc.
Databáze:	OpenAIRE
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