| Popis: |
Polytrimethylene terephthalate(PTT) offers several advantageous properties such as good tensile strength, uniformity, stiffness, toughness, UV stability, resilience, stain resistance, outstanding elastic recovery, and dyeability. The effects of annealing temperature on physical properties and the structure of PTT filaments and yarn were investigated by measuring wide-angle X-ray diffraction (WAXD), density, optical birefringence, dynamic visco elasticity, and tensile testing. The intensity of maximum tan δ decreased and the temperature of maximum tan δ shifted to a higher temperature as the annealing temperature of filaments increased; however, it shifted to a lower temperature when the annealing tem- perature exceeded 130 o C. In addition, crystallinity, density and D-spacing of (010) crystal face increased as the annealing temperature increased. Optical birefringence and specific stress were almost constant up to 100 o C and then decreased above 130 o C. The shrinkage of PTT filament is 0 in boiling water when annealed above 130 o C; consequently, the use of annealed fiber above 130 o C can remove thermal instability when dyeing PTT fiber. In the case of yarns, the thermal sta- bility and physical properties of yarns showed the best effect when the ply number is less than 5, twist number is less than 400tpm, and the annealing time is 20minutes. |
