Bis[di(2-aminoethyl)amine-N,N',N']nickel(II) Chloride Monohydrate, a Redetermination

Autor:	Rosemary C. Hynes, C. J. Willis, Jagadese J. Vittal
Rok vydání:	1996
Předmět:	Inorganic chemistry General Medicine Crystal structure General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound Crystallography Octahedron chemistry Molecule Amine gas treating Hydrate Nickel(II) chloride Diffractometer Coordination geometry
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 52:1879-1881
ISSN:	0108-2701
DOI:	10.1107/s0108270196005835
Popis:	A redetermination of the structure of the title compound, [Ni(C 4 H 13 N 3 ) 2 ]Cl 2 .H 2 O, from diffractometer data leads to considerably more accurate geometric parameters than those obtained in a previous determination using film data. The coordination geometry around the Ni II atom in the [Ni(C 4 H 13 N 3 ) 2 ] 2+ cation is a distorted octahedron, with the Ni-N distances in the range 2.083(4)-2.166(4)A and the trans-N-Ni-N angles in the range 161.9(2)-177.5(2)°.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0ca4cc9891d33d0d50b922edc64c938e https://doi.org/10.1107/s0108270196005835 Zobrazit plný text záznamu Plný text