A diruthenium(III)-μ-oxo complex with amino acid bridges and its oxidative deamination in the presence of oxygen

Autor:	Amjad Hussain, M.M.Taqui Khan, R.B. Thorat, Debabrata Chatterjee, M.A. Moiz
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Reaction mechanism Stereochemistry Carboxylic acid Deamination chemistry.chemical_element Oxidative deamination Oxygen Catalysis Amino acid Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Carboxylate Physical and Theoretical Chemistry
Zdroj:	Polyhedron. 12:1437-1441
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(00)84579-9
Popis:	A stable diamagnetic complex of the type [(Ru111edta)2-μ-(amino-acidato)2-μ-oxo]6− is reported. The amino acid bridge in the presence of oxygen undergoes oxidative deamination, as shown by the formation of an α-keto acid and the liberation of NH3. The reaction is catalytic.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0ca076f2a4a9687fa2b85f5a6403e2ab https://doi.org/10.1016/s0277-5387(00)84579-9 Zobrazit plný text záznamu