Evidence from infrared spectra for the magnetic moment directions of CR cations in the spinel ferrites
Autor: | Guide Tang, Z.F. Shang, Z.Z. Li, C. M. Zhen, W. H. Qi, X.Y. Zhang, L.L. Lang, J. Xu |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Physica B: Condensed Matter. 463:26-29 |
ISSN: | 0921-4526 |
DOI: | 10.1016/j.physb.2015.01.035 |
Popis: | Infrared spectra of samples of the (A)[B] 2 O 4 spinel ferrites MFe 2 O 4 (M=Fe, Co, Ni, Cu, Cr) were investigated. It was found that the wave number ( ν 2 ) corresponding to B–O–B bond vibrations increases with decreasing magnetic moments ( μ m2 ) of the M 2+ cations, where the magnetic moment of Cr 2+ cation is assumed to be antiparallel to the other cations. This assumption is derived from a magnetic ordering model for spinel ferrites proposed recently by our group. |
Databáze: | OpenAIRE |
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