Decontamination of VX from Silicone: Characterization of Multicomponent Diffusion Effects
Autor: | Thomas P. Pearl, Brent A. Mantooth, Shawn M. Stevenson, Mark J. Varady |
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Rok vydání: | 2016 |
Předmět: |
chemistry.chemical_classification
Aqueous solution Chromatography General Chemical Engineering 02 engineering and technology General Chemistry Human decontamination Polymer 010402 general chemistry 021001 nanoscience & nanotechnology Elastomer Thermal diffusivity 01 natural sciences Industrial and Manufacturing Engineering 0104 chemical sciences chemistry.chemical_compound Silicone chemistry Chemical engineering Sodium hydroxide Methanol 0210 nano-technology |
Zdroj: | Industrial & Engineering Chemistry Research. 55:3139-3149 |
ISSN: | 1520-5045 0888-5885 |
Popis: | A continuum model of the transport and reaction processes occurring during decontamination of the chemical warfare agent (CWA) [2-(diisopropylamino)ethyl]-O-ethyl methylphosphonothioate (VX) absorbed in a silicone elastomer using solutions of sodium hydroxide in water, methanol, and mixtures thereof is presented. This model is based on the Maxwell-Stefan formulation of multicomponent diffusion along with the Flory-Huggins model of thermodynamic equilibrium in the polymer. It was found that, as methanol from the decontaminant absorbs into the silicone, the diffusivity of VX increases, accelerating its flux from the polymer phase to the decontaminant liquid phase. This composition dependence of the diffusivity was accurately described by the Vignes equation. Although the decontamination kinetics were slower for the methanol-based decontaminant in a well-stirred liquid-phase reactor, the overall performance was superior compared to the aqueous-based decontaminant due to the enhanced extraction rate from the ... |
Databáze: | OpenAIRE |
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