Low Interfacial Free Volume of Stubby Surfactants Stabilizes Water-in-Carbon Dioxide Microemulsions

Autor: Keith P. Johnston, Sandro R. P. da Rocha, Peter J. Rossky, P. Griffin Smith, Matthew T. Stone
Rok vydání: 2004
Předmět:
Zdroj: The Journal of Physical Chemistry B. 108:1962-1966
ISSN: 1520-5207
1520-6106
DOI: 10.1021/jp036224w
Popis: A novel paradigm for the design of surfactants for water/CO2 (W/C) microemulsions is presented. The paradigm focuses on the fractional free volume (FFV) available to CO2 at the interface. The FFV i...
Databáze: OpenAIRE