Spectroscopic and quantum chemical study of the structure of 4-aminopyrimidinoanthrones

Autor:	Yu. N. Zaitseva, B. E. Zaitsev, M. V. Kazankov, G. V. Sheban, O. A. Zotova, M. A. Ryabov
Rok vydání:	1994
Předmět:	Quantum chemical Absorption spectroscopy Chemistry medicine.drug_class Computational chemistry Organic Chemistry medicine Ionic bonding Tautomer Aminoketone
Zdroj:	Chemistry of Heterocyclic Compounds. 30:957-963
ISSN:	1573-8353 0009-3122
Popis:	4-Amino derivatives of pyrimidinoanthrone exist in the form of an aminoketone isomer in the crystalline state in neutral organic solutions, but in acid and alkaline media the tautomeric equilibrium is shifted toward formation of ionic forms of the iminohydroxyl tautomer. We present the characteristics of the IR and electronic absorption spectra and quantum chemical calculations for the neutral and ionic forms of the tautomers indicated above.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0c197279d3bfe096603bd0c2d32dffd2 https://doi.org/10.1007/bf01165036 Zobrazit plný text záznamu Full text from SpringerLink