Structural and X-ray powder diffraction studies of nano-structured lead(II) coordination polymer with η2 Pb⋯C interactions

Autor:	Haida Ahmadzadi, Farzin Marandi, Ali Morsali
Rok vydání:	2009
Předmět:	Diffraction Coordination sphere Chemistry Coordination polymer Coordination number Organic Chemistry X-ray Nanoparticle Infrared spectroscopy Biochemistry Inorganic Chemistry Crystallography chemistry.chemical_compound Materials Chemistry Physical and Theoretical Chemistry Powder diffraction
Zdroj:	Journal of Organometallic Chemistry. 694:3565-3569
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2009.07.016
Popis:	A new nano-sized Pb(II) one-dimensional coordination polymer with η 2 Pb–C interactions, [Pb 2 (μ 3 -ba) 2 (μ 2 -ba) 2 ] n ( 1 ) [ba − = benzylacetylacetonate] has been synthesized and characterized by SEM, X-ray powder diffraction, IR spectroscopy and elemental analyses. Single-crystal X-ray diffraction shows the coordination number of Pb(II) ions is seven and the lead atoms have hemidirected coordination sphere containing involving Pb⋯C interactions, C 2 O 7 Pb. PbO nanoparticles were obtained by calcinations of the nano-sized compound 1 at 600 °C.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0bfc447e0d87fc3166b7c2e2d9ff3d17 https://doi.org/10.1016/j.jorganchem.2009.07.016 Zobrazit plný text záznamu Full Text from ScienceDirect