Synthesis and Reactions of fac-Re(bpy)(CO)3(CH2OR) (R = H, Acetyl; bpy = 2,2‘-Bipyridyl)

Autor:	Dorothy H. Gibson, Bradley A. Sleadd, Ashwani Vij, Xiaolong Yin
Rok vydání:	1998
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Group (periodic table) Stereochemistry Organic Chemistry Hydroxymethyl Physical and Theoretical Chemistry
Zdroj:	Organometallics. 17:2689-2691
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om980102m
Popis:	Photoassisted reactions of fac-Re(bpy)(CO)3(CH2OR) (1, R = H; 2, R = OAc) and fac-Re(bpy)(CO)3CH2Ph (5) in MeOH provide fac-Re(bpy)(CO)3(OCH3) (3); 2 and 3 have been structurally characterized. Radical paths are indicated for 2 and 5; a nonradical path, involving photoassisted β-hydride elimination from the hydroxymethyl group, is proposed for 1.
Databáze:	OpenAIRE
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