A methyl viologen-containing cadmium crystalline material with photochromism and methylamine sensing properties
| Autor: | Li-Ping Xue, Zhao-Hao Li, Qiu-Pei Qin |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Coordination polymer chemistry.chemical_element Infrared spectroscopy 02 engineering and technology Crystal structure 010402 general chemistry 01 natural sciences Inorganic Chemistry Photochromism Electron transfer chemistry.chemical_compound Materials Chemistry medicine Physical and Theoretical Chemistry Cadmium Methylamine Viologen 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences Electronic Optical and Magnetic Materials Crystallography chemistry Ceramics and Composites 0210 nano-technology medicine.drug |
| Zdroj: | Journal of Solid State Chemistry. 293:121755 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/j.jssc.2020.121755 |
| Popis: | A cadmium crystalline material, namely, (MV)n[Cd(FDC)2]n (H2FDC = 2,5-furandicarboxylic acid; MV = methyl viologen) has been successfully constructed and fully characterized by single-crystal X-ray structure determination, IR spectra, elemental analyses and powder X-ray diffractions. The compound features a 2D layer structure, in which in situ generated MV2+ cations located in the interlayer. The MV-containing compound offers a type of electron transfer system, which endows the material with reversible photochromism activities originated from photo-induced electron transfer process. Moreover, the material could sense MA vapor with naked-eye colour change in a shorted time. |
| Databáze: | OpenAIRE |
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