Synthesis and properties of 5-phenoxyfurancarboxylic acids

Autor: Anton Beňo, Jaroslav Kováč, Viera Knoppová
Rok vydání: 1980
Předmět:
Zdroj: Collection of Czechoslovak Chemical Communications. 45:910-913
ISSN: 1212-6950
0010-0765
Popis: Furancarboxylic acids were prepared by oxidation with Ag2O of the corresponding 5-(X-phenoxy)-2-furaldehydes (X = 4-OCH3, 4-SCH3, 3-NHCOCH3, 4-Cl, 4-Br, 4-COOC2H5, 3-NO2, and 4-NO2. The appearing pKa values of the synthesized acids were determined by potentiometric titration. The transfer effect of the substituents through the oxygen bridge is discussed and the transfer coefficient is compared with π' values of other linking groups in the furan series.
Databáze: OpenAIRE