Insertion reactions of organic anhydrides into the Cu–O bond of [CuOtBu]: syntheses and structures of functionalised copper (I) and copper (II) carboxylates

Autor:	Lukasz Ponikiewski, Alexander Rothenberger
Rok vydání:	2005
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Insertion reaction Polymer chemistry Materials Chemistry Organic chemistry Maleic anhydride chemistry.chemical_element Crystal structure Physical and Theoretical Chemistry Copper
Zdroj:	Inorganica Chimica Acta. 358:1322-1326
ISSN:	0020-1693
DOI:	10.1016/j.ica.2004.10.019
Popis:	The insertion reaction of maleic anhydride into the Cu–O bond in [CuOtBu] produced the complexes [Cu2(CO2C2H2CO2tBu)4 · dme] (1), [Cu(CO2C2H2CO2tBu)2 · tmeda] (2) and [Cu2(CO2C2H2CO2tBu)2 · dppm]2 (3) (dme = 1,2-dimethoxyethane; tmeda = N1,N1,N2,N2-tetramethylethane-1,2-diamine; dppm = bis(diphenylphosphino)methane). This reaction represents a useful synthetic strategy for a range of functionalised Cu(I) and Cu(II) carboxylates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0b9637262899da54d15a2b7ab6931918 https://doi.org/10.1016/j.ica.2004.10.019 Zobrazit plný text záznamu Full Text from ScienceDirect