Autor: |
Young Do Kim, Won Jung Kim, Accepted October, Received August, Do Sung Huh, Bong Seong Kim |
Rok vydání: |
2011 |
Předmět: |
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Zdroj: |
Bulletin of the Korean Chemical Society. 32:4221-4226 |
ISSN: |
0253-2964 |
DOI: |
10.5012/bkcs.2011.32.12.4221 |
Popis: |
Honeycomb-patterned polyvinypyrrolidone (PVP) thin films coated with nanometer-sized silver particles were prepared using honeycomb-patterned polystyrene (PS) template films fabricated by casting a polystyrene solution under humid condition. Silver was first metallized on the patterned PS films via silver nitrate () reduction using tetrathiafulvalene (TTF) and a small amount of PVP as the reductant and dispersing agent, respectively. The effects of , TTF, and PVP solution concentrations during the reduction process in acetonitrile were determined to obtain a uniform silver-coated honeycomb-patterned PS film. Second, the silver-metallized patterned porous PS films were filled with high PVP concentration solutions via the spincoating process. Silver-coated patterned PVP films were obtained by peeling off the PVP layer from the template PS film after drying. The results show that the honeycomb-patterned PVP films uniformly coated with silver particles are conveniently obtained using the silver-coated patterned PS template, although the direct fabrication of these films using water droplets under humid conditions was not feasible because of the water solubility of PVP. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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