ChemInform Abstract: Further Insight into the Photochemical Behavior of Aromatic γ,δ-Epoxy Ketones: A New Approach for Synthesis of 4-Methyleneisochromanols
Autor: | Bing Li, Chao Yang, Weitao Xia, Wujiong Xia |
---|---|
Rok vydání: | 2016 |
Předmět: | |
Zdroj: | ChemInform. 47 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.201602133 |
Popis: | The photochemical behavior of methyl-substituted aromatic γ,δ-epoxy ketones was investigated by irradiation with a 500 W high-pressure mercury lamp in benzene which led to the formation of 4-methyleneisochromanols through δ-hydrogen abstraction–epoxy rearrangement–1,5-biradical cyclization reactions. |
Databáze: | OpenAIRE |
Externí odkaz: |