Synthesis and characterization of both enantiomers of trans-1,2-di-(2-hydroxy-2-propyl)-cyclobutane

Autor:	Hans-Dieter Scharf, Frank W. Curtius
Rok vydání:	1996
Předmět:	Inorganic Chemistry Cerium chemistry.chemical_compound Chemistry Stereochemistry Organic Chemistry chemistry.chemical_element Physical and Theoretical Chemistry Enantiomer Ring (chemistry) Catalysis Cyclobutane
Zdroj:	Tetrahedron: Asymmetry. 7:2957-2961
ISSN:	0957-4166
DOI:	10.1016/0957-4166(96)00386-2
Popis:	Both enantiomers of the title compound are synthesized for the first time in four steps including a [2+2]-photocycloaddition to build up the cyclobutane backbone and a cerium supported reductive permethylation. During the cerium supported process a complete and selective change in the configuration of the cyclobutane ring takes place. The substituents are transformed from the cis - to the trans -geometry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0b75c6f70939e9a8c25e57abc8f85e20 https://doi.org/10.1016/0957-4166(96)00386-2 Zobrazit plný text záznamu Full Text from ScienceDirect