Intercalation chemistry of aluminium dihydrogentriphosphate with weak bases and polymerization of aniline between its layers

Autor:	Masa Karasu, Hideyuki Tagaya, Noriyuki Kuramoto, Jun-ichi Kadokawa, Koji Chiba, Shigemitsu Sato
Rok vydání:	1994
Předmět:	Nanocomposite Bilayer Intercalation (chemistry) Inorganic chemistry chemistry.chemical_element General Chemistry Condensed Matter Physics chemistry.chemical_compound Aniline chemistry Polymerization Aluminium Polyaniline Monolayer Food Science
Zdroj:	Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. 18:193-204
ISSN:	1573-1111 0923-0750
DOI:	10.1007/bf00705821
Popis:	Weak bases such as 2-aminopyridine, 4-aminopyridine,o-phenylenediamine,p-phenylenediamine and aniline were intercalated into aluminium dihydrogentriphosphate (ADHP) using ultrasonic wave irradiation. The interlayer spacing of ADHP increased from 8.1 A to 12.4–20.0 A. From the values of the layer expansions and host/guest ratios, bilayer or monolayer structures were considered. Chemical oxidation of the aniline resulted in the formation of polyaniline in the ADHP layers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0b738262552caa805b17747f6fa94e2e https://doi.org/10.1007/bf00705821 Zobrazit plný text záznamu Full text from SpringerLink