Synthesis of Fencholenic Aldehyde from α-pinene Epoxide on Modified Clays

Autor:	A.Yu. Sidorenko, Vladimir Agabekov, E. V. Koroleva, A.V. Kravtsova, A. V. Baranovskii, Zh. V. Ignatovich, A. L. Ermolinskaya
Rok vydání:	2018
Předmět:	chemistry.chemical_classification Pinene 010405 organic chemistry Epoxide Plant Science General Chemistry 010402 general chemistry 01 natural sciences Aldehyde General Biochemistry Genetics and Molecular Biology 0104 chemical sciences NMR spectra database chemistry.chemical_compound chemistry Organic chemistry Isomerization Two-dimensional nuclear magnetic resonance spectroscopy
Zdroj:	Chemistry of Natural Compounds. 54:893-897
ISSN:	1573-8388 0009-3130
DOI:	10.1007/s10600-018-2506-9
Popis:	The conditions for isomerization of α-pinene epoxide (2,3-epoxypinane) on modified clays that gave comparatively high contents (33.0%) of fencholenic (iso-campholenic) aldehyde in the product mixture were determined. An effective method for isolating it was proposed. The structure of iso-campholenic aldehyde was confirmed by analyzing 2D NOESY and HMBC NMR spectra.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0b4d34bb2c1b05ff87113f2c9185f68a https://doi.org/10.1007/s10600-018-2506-9 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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