Liquid-phase codimerization of ethylene with propylene on nickel carbonyl triphenylphosphine complex anchored on surface of aluminum oxide

Autor:	N. V. Volchkov, D. B. Furman, O. V. Bragin, V. É. Vasserberg, L. A. Makhlis, S. A. Chernov
Rok vydání:	1983
Předmět:	chemistry.chemical_compound Ethylene Monomer chemistry Yield (chemistry) Nickel Carbonyl Inorganic chemistry Copolymer Molar mass distribution General Chemistry Triphenylphosphine Catalysis
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:2414-2416
ISSN:	1573-9171 0568-5230
Popis:	1. The catalytic system Ni(CO)x(PPh3)y/A12O3-Et3Al2Cl3 (x + y=4) is active at 40°C in copolymerization of ethylene with propylene over a broad range of monomer concentrations. 2. The molecular weight distribution and structural composition of the products depends on the ratio γo=[C3H6]/[C2H4]o. The maximum yield of C5 olefins is 45% with γo=7–32. 3. Under conditions of codimerization, ethylene accelerates the dimerization of propylene quite substantially.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0b4aff17d0f11725a513f2422e439be1 https://doi.org/10.1007/bf00954466 Zobrazit plný text záznamu Full text from SpringerLink