A new convenient asymmetric approach to herbarumin III

Autor: Shi Jun Da, Xue Song Chen, Bo Yan Xu, Zhi Xiang Xie, Ying Li, Li Hong Yang
Rok vydání: 2007
Předmět:
Zdroj: Chinese Chemical Letters. 18:255-257
ISSN: 1001-8417
DOI: 10.1016/j.cclet.2007.01.035
Popis: The asymmetric total synthesis of herbarumin III 3, a naturally occurred phytotoxin, along with 8-epi-herbarumin III 22, was succeeded in 12 steps from n-butyraldehyde based on Brown's asymmetric allylation, taking modified Julia olefination and Yamaguchi's macro-lactonization as key steps.
Databáze: OpenAIRE