Enantioselective N-Heterocyclic Carbene Catalysis via Acyl Azolium without Exogenous Oxidants

Autor:	Rachel M. Gillard, David W. Lupton, Jing Cao, Azar Jahanbakhsh, Martin Breugst
Rok vydání:	2020
Předmět:	chemistry.chemical_compound 010405 organic chemistry Chemistry Enantioselective synthesis lipids (amino acids peptides and proteins) General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry Carbene Catalysis 0104 chemical sciences
Zdroj:	ACS Catalysis. 10:11791-11796
ISSN:	2155-5435
DOI:	10.1021/acscatal.0c02705
Popis:	An approach to the α,β-unsaturated acyl azolium has been developed that exploits N-heterocyclic carbenes (NHCs) and acyl fluorides, without additional oxidants, bases, or preactivated pro-nucleophi...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0b231005ce569cfa0e8fd2178260140e https://doi.org/10.1021/acscatal.0c02705 Zobrazit plný text záznamu