Microemulsion co-polymerization of methyl methacrylate with acrylonitrile
| Autor: | R. Sriram, G. V. Ramana Reddy, C. Magesh |
|---|---|
| Rok vydání: | 2005 |
| Předmět: |
Polymers and Plastics
Chemistry General Chemical Engineering Potassium food and beverages chemistry.chemical_element General Chemistry chemistry.chemical_compound Pulmonary surfactant Polymerization Emulsion Polymer chemistry Materials Chemistry Reactivity (chemistry) Microemulsion Acrylonitrile Methyl methacrylate |
| Zdroj: | Designed Monomers and Polymers. 8:75-89 |
| ISSN: | 1568-5551 |
| DOI: | 10.1163/1568555053084195 |
| Popis: | Microemulsion (M.E.) and conventional emulsion (C.E.) co-polymerizations of methyl methacrylate (MMA) with acrylonitrile (AN) have been carried out at 70°C by employing n-pentanol (PA) as co-surfactant along with sodium lauryl sulphate (SLS) as surfactant in the reaction medium and potassium persulphate (KPS) as initiator. The co-polymers are characterized by FT-IR, NMR, TG/DTA and GPC. The reactivity ratios are evaluated by employing the graphical procedures of Fineman–Ross, Kellen-Tudos and Mayo–Lewis. The reactivity ratios, r MMA and r AN, for the M.E. co-polymerization of MMA with AN as calculated using the Kellen-Tudos method are 1.83 ± 0.02 and 0.20 ± 0.02, and 2.20 ± 0.02 and 0.18 ± 0.02 for the C.E. co-polymerization of MMA with AN, respectively. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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