Sb atom reconstruction induced by atomic hydrogen interaction with Si(111)3×3–Sb surface
Autor: | Toshiaki Fujino, Osamu Kubo, Mitsuhiro Katayama, Kenjiro Oura, Jeong-Tak Ryu |
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Rok vydání: | 2005 |
Předmět: |
Hydrogen
Chemistry chemistry.chemical_element Surfaces and Interfaces Condensed Matter Physics Surfaces Coatings and Films law.invention Metal Elastic recoil detection Crystallography law Phase (matter) visual_art Monolayer Atom Materials Chemistry visual_art.visual_art_medium Scanning tunneling microscope Surface reconstruction |
Zdroj: | Surface Science. 581:17-23 |
ISSN: | 0039-6028 |
Popis: | We observed the reconstruction of a Si ( 1 1 1 ) 3 × 3 – Sb surface phase induced by atomic hydrogen (H) using scanning tunneling microscopy and time-of-flight elastic recoil detection analysis. When a Si ( 1 1 1 ) 3 × 3 – Sb surface was exposed to H at room temperature, depending on H amount, the surface structure was transformed into a 2 × 1 phase, the surface reaction in which started at the original domain boundaries and surface defects. In such a process, most Sb atoms were not replaced with hydrogen atoms, so that the agglomeration of Sb atoms was not observed. The hydrogen coverage of the reacted surface was as low as 0.1–0.2 monolayers, and about one-half the amount of H seem to form bonds with Sb atoms. These results are quite different from metal island formation induced by H on other metal/Si(1 1 1) surfaces. |
Databáze: | OpenAIRE |
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